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title: How Garbage Kickstarted The Modern Chemical Industry
description: Scientific experiments don't always happen according to the hypothesis, and sometimes failed experiments can even lead to new innovations.
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article:published_time: 2014-11-10T20:36:09.000Z
article:modified_time: 2026-10-01T09:03:19.176Z
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og:title: How garbage kickstarted the modern chemical industry
og:description: Scientific experiments don't always happen according to the hypothesis, and sometimes failed experiments can even lead to new innovations.
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![](https://static.time.com/v3/assets/bltea6093859af6183b/bltcacfc68e277ebeda/69876808a988ca586b6aaa60/link-cfm.jpeg?branch=production&width=1200&quality=75&auto=webp&crop=16:9)


# How Garbage Kickstarted the Modern Chemical Industry

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## Video: Accidental Discoveries That Changed The World - Reactions

[Watch (HLS stream): Accidental Discoveries That Changed The World - Reactions](https://cdn.jwplayer.com/manifests/kvL2Njj6.m3u8) (5:37)

![Accidental Discoveries That Changed The World - Reactions](https://cdn.jwplayer.com/v2/media/kvL2Njj6/poster.jpg?width=720)

_Published 2014-11-10. Accidental Discoveries That Changed The World - Reactions_


by 

[TIME Video](https://time.com/author/time-video/)


## TIME Video


Nov 10, 2014 8:36 PM UTC

Accidental Discoveries That Changed The World - Reactions 

by 

[TIME Video](https://time.com/author/time-video/)


## TIME Video


Nov 10, 2014 8:36 PM UTC

Throughout the history of science, some of the most important breakthroughs have come about through happy accidents. This certainly bears true in the video above, courtesy of the [American Chemical Society](http://www.acs.org/content/acs/en.html), which explains how garbage kicked off the entire chemical industry.


## Transcript

[00:00] Isaac Asimov said it best. The most exciting phrase to hear
[00:03] in science, the one that heralds new discoveries is not
[00:06] Eureka, but, that's funny. Throughout the history
[00:10] of science, many major discoveries came accidentally.
[00:14] Sometimes they came from recognizing potential in an
[00:16] unexpected product or even in a failed recipe's waste,
[00:20] turning accident into serendipity. Other times discovery
[00:24] came out of pure desperation from a seemingly dead end
[00:27] experiment. See the entire modern chemical industry can
[00:31] be attributed to an accidental discovery that started with
[00:34] well, garbage. [ MUSIC ] In
[00:43] the 19th century there was a new kind of waste floating
[00:45] around: [ NOISE ] coal tar. This was a stinky, sticky,
[00:50] awful muck left over from turning coal into gas light. Before
[00:54] others figured out you could pave roads with the stuff, it
[00:57] was pretty much useless. Then the head of London's Royal
[01:01] College of Chemistry had an idea. August Wilhelm von
[01:04] Hofmann noticed that some of the stuff in coal tar was
[01:07] similar to the stuff in known medicines. If you got the
[01:10] chemistry right, he thought, the world would have cheap,
[01:13] easy cures for disease. So in 1856, he assigned
[01:18] 18- year- old William Perkin to Team Coal Tar. Perkin's job
[01:22] was to try to turn the gunk into quinine. Quinine was used
[01:26] to treat malaria but the drug had to be extracted from tree
[01:29] bark and that was time consuming and really annoying.
[01:33] Perkin knew that quinine and coal tar had similar chemical
[01:36] formulas so he figured take some of the stuff that's in coal
[01:39] tar that's similar to quinine. And some other stuff that looks
[01:43] like little bits of quinine then remove useless byproducts
[01:46] then Voila !, right? Yeah, not so much .>> Perkins
[01:52] first attempts got a reddish black powder instead of off white
[01:55] quinine crystals. So he made a couple of changes and
[01:58] tried it again. Instead of off white powder, he got an even
[02:01] blacker powder. Oh well, wash it out with a little alcohol
[02:04] and start it over right? But wait, when he added the alcohol
[02:08] the black powder produced a breathtaking purple. Perkin
[02:12] was inspired he somehow figured out this purple stuff could
[02:15] dye silk, Perkins saw dollar signs at the time purple
[02:19] dyed fabrics were made using exotic crushed snails, so
[02:23] only the very wealthy could afford to wear purple. Forget
[02:26] crushed snails. Perkin just made purple dye out of garbage.
[02:30] Perkin called this stuff mauve, after a French flower,
[02:33] because well, you know, trashy purple didn't quite sound
[02:36] appealing. Dreaming of broad profit margins, Perkin did
[02:40] what many entrepreneurs did. He quit, and started perhaps
[02:44] the first artificial dye factory. Within a few years mauve
[02:48] had two influential fashion fans: Queen Victoria, and
[02:52] Napoleon the Third's wife, Empress Eugénie. A fashion
[02:56] craze known as mauve measles erupted and suddenly, the
[02:59] middle class could afford a color beyond drab brown or
[03:02] off- white or gray. Perkins amassed a fortune of more than
[03:06] 100 million in today's dollars, and retired at the ripe old
[03:10] age of 36. On Perkins' lead, chemical factories sprang
[03:14] up, dumpster diving nature for treasure. And this led to
[03:18] even more profitable accidents. In 1878, Constantine
[03:22] Fallberg brought his gunky coal tar work home with him by
[03:26] not washing his hands. At dinner one night he found his
[03:30] bread incredible sweet. Fahlberg and his lab mates
[03:33] realized the source was a super sweet substance derived
[03:37] from coal tar residue they called saccharine. The
[03:40] accidental discoveries only grew in the 20th century. In late
[03:43] 1930s, Roy Plunkett at DuPont was working with
[03:46] refrigerants named fluorinated hydrocarbons. One day
[03:50] a new mix, annoyingly, solidified into a powder that made
[03:55] stuff slippery. Plunkett had stumbled on a new material
[03:58] called polytetrafluoroethylene, which DuPont marketed as
[04:03] Teflon. Teflon was awesome! It coated metal for a no- stick
[04:07] surface! And also, Teflon didn't conduct electricity, so it
[04:10] was great for wire coating. This led father and son team Bill
[04:14] and Bob Gore to work with Teflon to make computer
[04:17] cables. Bill and Bob discovered that Teflon didn't stretch
[04:20] evenly, making it hard to work with. Frustrated, Bob
[04:25] yanked on a hunk of heated teflon and suddenly it
[04:27] expanded to eight times it's size. Turns out,
[04:31] this heated stretched hunk was over 70 % air. So it could
[04:35] breathe easily while retaining the no stick properties of it's
[04:38] teflon parent. And if you wove this into a fabric, it proved
[04:43] fantastic for lightweight raincoats that don't wrap you in
[04:46] your own sauna. You know this material as Gore- Tex.
[04:52] So much of what we enjoy in the modern world came from
[04:54] accidental discoveries. Be it fashion cause causing mauve,
[04:59] sweeteners, teflon or Bortex. The Chemists behind this stuff
[05:03] were smart enough to recognise that they accidentally
[05:06] discovered something special. In the process, these
[05:09] moments became so much more than happy accidents.
[05:12] They became discoveries that changed the world. Hey
[05:16] chem heads thanks for watching if you want more Sam
[05:19] Keen check out a video he did for us on whether mega
[05:21] sharks still exist, and if you want more history check out
[05:24] five black chemists who changed the world, and regardless
[05:28] click that there subscribe button for more chemistry
[05:30] goodness every week. And a big thanks to the Chemical
[05:33] Heritage Foundation for helping us out with this video.

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